Spectroscopy
Principles of Spectroscopy Interaction of radiation and matter If matter is exposed to electromagnetic radiation, e.g. infrared light, the radiation can be absorbed, transmitted, reflected, scattered or undergo photoluminescence. Photoluminescence is a term used to designate a number of effects, including fluorescence, phosphorescence, and Raman scattering. Electromagnetic Spectrum Type of Radiation Frequency :Range (Hz):Wavelength Range:Type of Transition Gamma-rays 1020-1024 <10-12 m nuclear X-rays 1017-1020 1 nm-1 pm inner electron Ultraviolet 1015-1017 400 nm-1 nm outer electron Visible 4-7.5x1014 750 nm-400 nm outer electron Near-infrared 1x1014-4x1014 2.5 mm-750 nm outer electron molecular vibrations Infrared 1013-1014 25 mm-2.5 mm molecular vibrations Microwaves 3x1011-1013 1 mm-25 mm molecular rotations, electron spin flips* Radio waves <3x1011 >1 mm >1 mm TYPES OF OPTICAL INSTRUMENTS • Spectroscope: uses human eye as a detector • Spect...